The given reaction for the decomposition of Al2O3 is:
32Al2O3→34Al+O2
In this reaction, 34 moles of Al3+ ions are reduced to Al atoms. The number of electrons involved (n) can be calculated from either the reduction of Al or oxidation of O:
For Al: n=34×3=4 moles of electrons.
For O: 2O2−→O2+4e−, so n=4.
We know the relation between standard Gibbs energy and minimum external potential (E) required for electrolysis:
ΔrG=nFE
Given ΔrG=+960 kJ mol−1=960×103 J mol−1 and F≈96500 C mol−1.
960×103=4×96500×E
E=4×96500960×103=386000960000=2.487 V≈2.5 V
Hence, the minimum potential difference needed for the electrolytic reduction is 2.5 V.