For a first-order reaction, the rate is directly proportional to the concentration of the reactant: Rate=k[A].
Therefore, the ratio of rates at two different times is equal to the ratio of concentrations at those times:
Rate2Rate1=[A]2[A]1=0.030.04=34
The rate constant k can be calculated using the integrated rate equation between time t1 and t2:
k=t2−t12.303log[A]2[A]1
k=20−102.303log(34)=102.303(log4−log3)
k=102.303(0.6021−0.4771)=0.2303×0.1250≈0.0287 s−1
The half-life period (t1/2) is given by:
t1/2=k0.693=0.02870.693≈24.14 s.
Note: The exact calculation yields approximately 24.1 s (which was the intended option in the actual NEET exam), making 24.7 s the closest available choice or a likely typographical error in the provided options.