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NEET CHEMISTRYThe d-and f-Block ElementsMedium

Question

Zn gives H₂ gas with H₂SO₄ and HCl but not with HNO₃ because:

A

Zn acts as an oxidizing agent when it reacts with HNO₃

B

HNO₃ is weaker acid than H₂SO₄ and HCl

C

In the electrochemical series, Zn is above hydrogen

D

NO₃⁻ is reduced in preference to hydronium ion

Step-by-Step Solution

Zinc reacts with non-oxidizing acids like HCl and H₂SO₄ to evolve dihydrogen gas because Zinc has a lower standard reduction potential (E0=0.76VE^0 = -0.76 V) than hydrogen (E0=0.00VE^0 = 0.00 V), allowing it to reduce H+H^+ ions . However, HNO3HNO_3 is a strong oxidizing agent. When metals (with exceptions like Mg and Mn with very dilute acid) react with HNO3HNO_3, the hydrogen initially produced is oxidized to water, while the nitrate ion (NO3NO_3^-) is reduced to various nitrogen oxides (NO,NO2NO, NO_2, etc.) . Thermodynamically, the reduction of the nitrate ion occurs in preference to the reduction of the hydronium ion (H+H^+) to H2H_2 gas.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementsbecause

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