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NEET CHEMISTRYThe d-and f-Block ElementsEasy

Question

Zr (Z=40Z = 40) and Hf (Z=72Z = 72) have similar atomic and ionic radii because of:

A

Lanthanoid contraction

B

Having similar chemical properties

C

Belonging to the same group

D

Diagonal relationship

Step-by-Step Solution

The elements of the second (4d) and third (5d) transition series exhibit similar atomic and ionic radii (e.g., Zr = 160 \pm and Hf = 159 pm). This similarity is due to the phenomenon of lanthanoid contraction . The filling of 4f orbitals before the 5d orbitals results in a poor shielding effect, which causes a regular decrease in atomic radii. This decrease essentially compensates for the expected increase in atomic size with an increasing atomic number down the group, leading to almost identical radii for Zirconium (Zr) and Hafnium (Hf) .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementssimilaratomicbecause

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