The potential energy between two atoms in a molecule is given by U(x)=x12a−x6b, where a and b are positive constants and x is the distance between the atoms. The atoms are in stable equilibrium when:
A
x=15b11a
B
x=12ba
C
x=0
D
x=1b2a
Step-by-Step Solution
For stable equilibrium, the net force acting on the particles must be zero, and the potential energy must be at a minimum.
The force F is related to the potential energy U(x) by the equation:
F=−dxdU
Given the potential energy function U(x)=x12a−x6b=ax−12−bx−6, we differentiate it with respect to x:
dxdU=−12ax−13−(−6)bx−7=−x1312a+x76b
For equilibrium, the force F=0, which means dxdU=0:
−x1312a+x76b=0x76b=x1312ax6=6b12a=b2ax=b2a
To confirm it is a point of stable equilibrium, the second derivative dx2d2U must be positive (indicating a potential energy minimum).
dx2d2U=156ax−14−42bx−8
Substituting x6=b2a into this derivative yields a positive value, confirming stable equilibrium. Thus, the atoms are in stable equilibrium when x=b2a.
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NEET PHYSICS: "The potential energy between two atoms in a molecule is given by $U(x) = \frac{a}{x^{12}} - \frac{b}{x^6}$, where $a$ an..." — Solved MCQ | TopperSquare