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In which of the following compounds is an intramolecular hydrogen bond present?
Which of the following has the minimum bond length?
Among the following, the pair in which the two species are not isostructural is:
Which of these following methods is the most suitable for disposal of nuclear waste?
For the gas phase reaction, $\text{PCl}_5\text{(g)} \rightleftharpoons \text{PCl}_3\text{(g)} + \text{Cl}_2\text{(g)}$, which of the following conditions is correct?
One mole of an ideal gas at $300\text{ K}$ is expanded isothermally from an initial volume of $1\text{ litre}$ to $10\text{ litres}$. The $\Delta E$ for this process is: ($R = 2\text{ cal mol}^{-1}\text{K}^{-1}$)
Which of the following compounds has the lowest melting point?
What is the amount of work done by an ideal gas, if the gas expands isothermally from $10^{-3} \text{ m}^3$ to $10^{-2} \text{ m}^3$ at $300 \text{ K}$ against a constant pressure of $10^5 \text{ N m}^{-2}$?
In the hydrocarbon $\overset{6}{C}H_3-\overset{5}{C}H=\overset{4}{C}H-\overset{3}{C}H_2-\overset{2}{C}\equiv\overset{1}{C}H$, the state of hybridisation of carbons 1, 3 and 5 are in the following sequence:
In which of the following molecules are all the bonds not equal?
Match List-I (Equations/Conditions) with List-II (Type of processes) and select the correct option. **List-I (Equations)** (a) $K_p > Q$ (b) $T < \frac{\Delta H}{\Delta S}$ (for $\Delta H > 0$) (c) $K_p = Q$ (d) $T > \frac{\Delta H}{\Delta S}$ (for $\Delta H > 0$) **List-II (Type of processes)** (i) Non-spontaneous (ii) Equilibrium (iii) Spontaneous and endothermic (iv) Spontaneous
Consider the following species: CN$$^+$$, CN$$^-$$, NO and CN. The highest bond order associated with:
Arrange the following hydrides in the order of decreasing bond angle: (A) SbH$$_3$$ (B) AsH$$_3$$ (C) PH$$_3$$ (D) NH$$_3$$
The enthalpy of neutralization of which of the following acids and bases is nearly –13.6 Kcal [Roorkee 1999]
The heat of combustion of carbon to $\text{CO}_2$ is $-393.5 \text{ kJ/mol}$. The heat released upon the formation of $35.2 \text{ g}$ of $\text{CO}_2$ from carbon and oxygen gas is:
A system is changed from state A to state B by one path and from B to A by another path. If $E_{1}$ and $E_{2}$ are the corresponding changes in internal energy, then [Pb. PMT 2001]:
The work done to contract a gas in a cylinder is 462 joules. 128 joule energy is evolved in the process. What will be the internal energy change in the process? [MP PMT 2003]
The correct thermodynamic conditions for the spontaneous reaction at all temperatures is:
The freezing point depression constant ($K_f$) of benzene is 5.12 K kg $mol^{-1}$. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is (rounded off upto two decimal places) :
Choose the correct option for graphical representation of Boyle's law, which shows a graph of pressure vs. volume of a gas at different temperatures :