Question
The formation of the oxide ion O²⁻(g) from oxygen atom requires first an exothermic and then an endothermic step as shown below: O(g) + e⁻ → O⁻(g); \Delta H° = -141 kJ mol⁻¹ O⁻(g) + e⁻ → O²⁻(g); \Delta H° = +780 kJ mol⁻¹ Thus, the process of formation of O²⁻ in gas phase is unfavourable even though O²⁻ is isoelectronic with neon. It is due to the fact that:
Electron repulsion outweighs the stability gained by achieving noble gas configuration
O⁻ ion has comparatively smaller size than oxygen atom
Oxygen is more electronegative
Addition of electron in oxygen result in large size of the ion
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