back to directory
NEET CHEMISTRYChemical Bonding and Molecular StructureMedium

Question

An isostructural compound with XeF2XeF_2 among the following is:

A

ICl₂⁻

B

SbCl₃

C

BaCl₂

D

TeF₂

Step-by-Step Solution

  1. Analyze XeF2XeF_2:
  • Central atom Xenon (Xe) has 8 valence electrons.
  • It forms 2 sigma bonds with Fluorine.
  • Remaining electrons = 8−2=68 - 2 = 6 (3 lone pairs).
  • Structure: 2 Bond Pairs + 3 Lone Pairs →\rightarrow Linear geometry (Lone pairs occupy equatorial positions in trigonal bipyramidal electron geometry).
  1. Analyze Option A (ICl2−ICl_2^-):
  • Central atom Iodine (I) has 7 valence electrons.
  • Negative charge adds 1 electron →\rightarrow Total 8 valence electrons on the central shell context.
  • It forms 2 sigma bonds with Chlorine.
  • Remaining electrons = 8−2=68 - 2 = 6 (3 lone pairs).
  • Structure: 2 Bond Pairs + 3 Lone Pairs →\rightarrow Linear geometry.
  • Since both have the same structure (Linear) and hybridization (sp3dsp^3d), they are isostructural.
  1. Analyze other options:
  • SbCl3SbCl_3: 3 Bond Pairs + 1 Lone Pair →\rightarrow Trigonal Pyramidal.
  • BaCl2BaCl_2: Ionic/Linear (but typically considered distinct from covalent VSEPR analogs in this context).
  • TeF2TeF_2: 2 Bond Pairs + 2 Lone Pairs →\rightarrow Bent/Angular.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structureisostructuralcompoundfollowing

More Chemical Bonding and Molecular Structure Questions

View all

Which of the following species has a linear shape?

A.$\text{NO}_2^-$
B.$\text{SO}_2$
C.$\text{NO}_2^+$
D.$\text{O}_3$
MediumSolve

Which of the following is a paramagnetic compound?

A.N₂
B.H₂
C.Li₂
D.O₂
EasySolve

A molecule having the maximum dipole moment among the following is -

A.$\text{CO}_2$
B.$\text{CH}_4$
C.$\text{NH}_3$
D.$\text{NF}_3$
MediumSolve

Which orbital does the additional electron occupy when $O_{2}$ is converted to the $O_{2}^{-}$ ion?

A.$\pi$ orbital
B.$\sigma^{*}$ orbital
C.$\sigma$ orbital
D.$\pi^{*}$ orbital
MediumSolve

Which of the following pairs share both isoelectronicity and isostructural characteristics? $\text{NO}_3^-$, $\text{CO}_3^{2-}$, $\text{ClO}_3^-$, $\text{SO}_3$

A.$\text{NO}_3^-$, $\text{CO}_3^{2-}$
B.$\text{SO}_3$, $\text{NO}_3^-$
C.$\text{ClO}_3^-$, $\text{CO}_3^{2-}$
D.$\text{CO}_3^{2-}$, $\text{ClO}_3^-$
MediumSolve

A paramagnetic molecule among the following is:

A.O₂⁻
B.CN⁻
C.NO⁺
D.CO
EasySolve

Consider the given compound: In the given options, the following for the above compound are, respectively: (i) $sp^{2}$ hybridised carbon atoms and (ii) $\pi$ bonds.

A.7, 5
B.8, 6
C.7, 6
D.8, 5
MediumSolve

Increasing order of bond length is:

A.$NO^{-} < NO < NO^{+} < O_{2}^{-}$
B.$O_{2}^{-} < NO < NO^{-} < NO^{+}$
C.$O_{2}^{-} < NO^{-} < NO < NO^{+}$
D.$NO^{+} < NO < NO^{-} < O_{2}^{-}$
MediumSolve

Why 32,000+ students choose TopperSquare

Everything you need to crack NEET

15,000+ Chapter MCQs

Physics, Chemistry, Biology — chapter-wise, topic-wise practice

AI Performance Analytics

Know your weak topics. Get a personalised study plan.

Full NEET Mock Tests

180 questions, timed, with detailed score analysis

PYQ Sets 2010–2024

15 years of past papers with solved explanations

Start Practising Free

No credit card · 30-second signup · Free forever plan included

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →

Explore more subjects:Physics MCQs•Chemistry MCQs•Biology MCQs•Botany MCQs•Zoology MCQs•NEET Mock Tests•NEET PYQs