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NEET CHEMISTRYP Block ElementsMedium

Question

For the reaction PbO2PbOPbO_2 \rightarrow PbO, ΔG298<0\Delta G_{298} < 0, and for the reaction SnO2SnOSnO_2 \rightarrow SnO, ΔG298>0\Delta G_{298} > 0. The most probable oxidation states of Pb and Sn will be respectively:

A

Pb4+,Sn4+Pb^{4+}, Sn^{4+}

B

Pb4+,Sn2+Pb^{4+}, Sn^{2+}

C

Pb2+,Sn2+Pb^{2+}, Sn^{2+}

D

Pb2+,Sn4+Pb^{2+}, Sn^{4+}

Step-by-Step Solution

The given ΔG\Delta G values indicate the spontaneity of the decomposition reactions.

  1. Lead (Pb): The reaction PbO2(+4)PbO(+2)PbO_2 (+4) \rightarrow PbO (+2) has ΔG<0\Delta G < 0, meaning it is spontaneous. This indicates that the +2 oxidation state is thermodynamically more stable than the +4 state for Lead. This is due to the inert pair effect, where the 6s26s^2 electrons are reluctant to participate in bonding.
  2. Tin (Sn): The reaction SnO2(+4)SnO(+2)SnO_2 (+4) \rightarrow SnO (+2) has ΔG>0\Delta G > 0, meaning it is non-spontaneous. This indicates that the +4 oxidation state is more stable than the +2 state for Tin.

Thus, the most characteristic states are Pb(+2) and Sn(+4).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from P Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYP Block Elementsreactionrightarrowreactionrightarrowprobable

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