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NEET CHEMISTRYGeneralMedium

Question

Given below are two statements Statement I: In the coagulation of a negative sol, the flocculating power of the three given ions is in the order Al3+>Ba2+>Na+Al^{3+} > Ba^{2+} > Na^+ Statement II: In the coagulation of a positive sol, the flocculating power of the three given salts is in the order NaCl<Na2SO4<Na3PO4NaCl < Na_2SO_4 < Na_3PO_4 In the light of the above statements, choose the most appropriate answer from the options given below

A

Statement I is correct but Statement II is incorrect

B

Statement I is incorrect but Statement II is correct

C

Both Statement I and Statement II are correct

D

Both Statement I and Statement II are incorrect

Step-by-Step Solution

According to the Hardy-Schulze rule, the flocculating power of an ion increases with the increase in the magnitude of the charge on the ion. For a negatively charged colloid, the flocculating power of cations follows the order Al3+>Ba2+>Na+Al^{3+} > Ba^{2+} > Na^+. For a positively charged colloid, the flocculating power of anions follows the order of their valency, which is Cl<SO42<PO43Cl^- < SO_4^{2-} < PO_4^{3-}, hence the order of salts is NaCl<Na2SO4<Na3PO4NaCl < Na_2SO_4 < Na_3PO_4. Both statements are correct.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from General. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYstatementsstatementcoagulationnegativeflocculating

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