back to directory
NEET CHEMISTRYP Block ElementsMedium

Question

The most characteristic oxidation state for lead and tin is, respectively:

A

+4, +2

B

+2, +4

C

+4, +4

D

+2, +2

Step-by-Step Solution

In Group 14 elements, the general valence shell electronic configuration is ns2np2ns^2np^2, allowing for +2 and +4 oxidation states. As we move down the group from Carbon to Lead, the stability of the +4 oxidation state decreases, while the stability of the +2 oxidation state increases due to the inert pair effect (the reluctance of the inner ns2ns^2 electrons to participate in bonding due to poor shielding by dd and ff orbitals) [Source 19].

  1. Lead (Pb): For lead, the inert pair effect is very strong. Consequently, the +2 oxidation state is its most characteristic and stable state. Compounds in the +4 state (like PbO2PbO_2) are strong oxidising agents as they tend to revert to the +2 state.
  2. Tin (Sn): For tin, the +4 oxidation state is more stable and characteristic. Sn(II) compounds act as reducing agents because they readily lose electrons to form the stable Sn(IV) species.

Therefore, the correct order is +2 for Lead and +4 for Tin.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from P Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYP Block Elementscharacteristicoxidationrespectively

More P Block Elements Questions

View all

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →