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NEET CHEMISTRYAlcohols, Phenols and EthersMedium

Question

Which amongst the following will be most readily dehydrated under acidic conditions?

A

Option 1 (Structure Missing)

B

Option 2 (Structure Missing)

C

Option 3 (Structure Missing)

D

Option 4

Step-by-Step Solution

The dehydration of alcohols under acidic conditions proceeds via an E1 mechanism involving the formation of a carbocation intermediate. The rate-determining step is the formation of this carbocation. Therefore, the alcohol that forms the most stable carbocation will be the most readily dehydrated.

Reactivity Order:

  1. Carbocation Stability: The stability order is Tertiary (33^{\circ}) > Secondary (22^{\circ}) > Primary (11^{\circ}).
  2. Resonance: Alcohols that form allylic or benzylic carbocations are even more reactive due to resonance stabilization.
  3. Electron Withdrawing Groups: Presence of electron-withdrawing groups (like NO2-NO_2 or C=O-C=O) adjacent to the carbocation center destabilizes it, reducing reactivity.

Option 4 likely contains a structure that yields a stable tertiary carbocation or one stabilized by resonance, making it the most reactive.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Ethersamongstfollowingreadilydehydratedacidic

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