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neet CHEMISTRYHard

Which of the following statements are INCORRECT? A. All the transition metals except scandium form MO oxides which are ionic. B. The highest oxidation number corresponding to the group number in transition metal oxides is attained in Sc2O3Sc_2O_3 to Mn2O7Mn_2O_7. C. Basic character increases from V2O3V_2O_3 to V2O4V_2O_4 to V2O5V_2O_5. D. V2O4V_2O_4 dissolves in acids to give VO43VO_4^{3-} salts. E. CrOCrO is basic but Cr2O3Cr_2O_3 is amphoteric. Choose the correct answer from the options given below:

A

A and E only

B

B and D only

C

C and D only

D

B and C only

Step-by-Step Solution

Statement C is incorrect because basic character decreases as oxidation state increases (from V2O3V_2O_3 to V2O5V_2O_5). Statement D is incorrect because V2O4V_2O_4 dissolves in acids to give VO2+VO^{2+} (vanadyl) ions, not VO43VO_4^{3-} (which is formed in basic conditions).

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