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NEET CHEMISTRYEquilibriumEasy

Question

Among the following pairs of solutions, the one which is not an acidic buffer is:

A

HClO4HClO_4 and NaClO4NaClO_4

B

CH3COOHCH_3COOH and CH3COONaCH_3COONa

C

H2CO3H_2CO_3 and Na2CO3Na_2CO_3

D

H3PO4H_3PO_4 and Na3PO4Na_3PO_4

Step-by-Step Solution

An acidic buffer solution is prepared by mixing a weak acid and its salt with a strong base .

  • CH3COOHCH_3COOH, H2CO3H_2CO_3, and H3PO4H_3PO_4 are all weak acids, and their corresponding sodium salts will form acidic buffer solutions.
  • HClO4HClO_4 (perchloric acid), on the other hand, is a very strong acid . A mixture of a strong acid and its salt does not act as a buffer solution. Therefore, HClO4HClO_4 and NaClO4NaClO_4 is not an acidic buffer.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Equilibrium. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYEquilibriumfollowingsolutionsacidicbuffer

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Consider the following reaction: $\text{A}_2(g) + \text{B}_2(g) \rightleftharpoons 2\text{AB}(g)$. At equilibrium, the concentrations of $[\text{A}_2] = 3.0 \times 10^{–3} \text{ M}$; $[\text{B}_2] = 4.2 \times 10^{–3} \text{ M}$ and $[\text{AB}] = 2.8 \times 10^{–3} \text{ M}$. The value of $K_c$ for the above-given reaction in a sealed container at $527^\circ\text{C}$ is:

A.3.9
B.0.6
C.4.5
D.2
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Amongst the given options, which of the following molecules/ions acts as a Lewis acid?

A.$\text{OH}^-$
B.$\text{NH}_3$
C.$\text{H}_2\text{O}$
D.$\text{BF}_3$
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Boric acid is an acid because its molecule

A.contains replaceable H⁺ ion
B.gives up a proton
C.accepts OH⁻ from water releasing proton
D.combines with proton from water molecule
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The following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations. pH of which one of them will be equal to 1?

A.$60 \text{ mL } \frac{M}{10} \text{ HCl } + 40 \text{ mL } \frac{M}{10} \text{ NaOH}$
B.$55 \text{ mL } \frac{M}{10} \text{ HCl } + 45 \text{ mL } \frac{M}{10} \text{ NaOH}$
C.$75 \text{ mL } \frac{M}{5} \text{ HCl } + 25 \text{ mL } \frac{M}{5} \text{ NaOH}$
D.$100 \text{ mL } \frac{M}{10} \text{ HCl } + 100 \text{ mL } \frac{M}{10} \text{ NaOH}$
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The tendency of $BF_3$, $BCl_3$ and $BBr_3$ to behave as Lewis acid decreases in the sequence:

A.$BCl_3 > BF_3 > BBr_3$
B.$BBr_3 > BCl_3 > BF_3$
C.$BBr_3 > BF_3 > BCl_3$
D.$BF_3 > BCl_3 > BBr_3$
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A compound $\text{BA}_2$ has $K_{sp} = 4 \times 10^{-12}$. Solubility of this compound will be:

A.$10^{-3} \text{ mol/L}$
B.$10^{-4} \text{ mol/L}$
C.$10^{-5} \text{ mol/L}$
D.$10^{-6} \text{ mol/L}$
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What is the molarity of the saturated solution if the solubility product for a salt of type AB is $4 \times 10^{-8}$?

A.$2 \times 10^{-4} \text{ mol/L}$
B.$16 \times 10^{-16} \text{ mol/L}$
C.$2 \times 10^{-16} \text{ mol/L}$
D.$4 \times 10^{-4} \text{ mol/L}$
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In qualitative analysis, the metals of Group I can be separated from other ions by precipitating them as chloride salts. A solution initially contains $\text{Ag}^+$ and $\text{Pb}^{2+}$ at a concentration of $0.10 \text{ M}$. Aqueous $\text{HCl}$ is added to this solution until the $\text{Cl}^-$ concentration is $0.10 \text{ M}$. What will the concentration of $\text{Ag}^+$ and $\text{Pb}^{2+}$ at equilibrium? ($K_{sp}$ for $\text{AgCl} = 1.8 \times 10^{-10}$, $K_{sp}$ for $\text{PbCl}_2 = 1.7 \times 10^{-5}$)

A.$[\text{Ag}^+] = 1.8 \times 10^{-11} \text{ M}; [\text{Pb}^{2+}] = 1.7 \times 10^{-4} \text{ M}$
B.$[\text{Ag}^+] = 1.8 \times 10^{-7} \text{ M}; [\text{Pb}^{2+}] = 1.7 \times 10^{-6} \text{ M}$
C.$[\text{Ag}^+] = 1.8 \times 10^{-11} \text{ M}; [\text{Pb}^{2+}] = 8.5 \times 10^{-5} \text{ M}$
D.$[\text{Ag}^+] = 1.8 \times 10^{-9} \text{ M}; [\text{Pb}^{2+}] = 1.7 \times 10^{-3} \text{ M}$
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