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NEET CHEMISTRYHydrocarbonsMedium

Question

Among the following, the correct example of a free-radical substitution reaction is:

A

Option 1 (Structure missing)

B

Option 2 (Structure missing)

C

Option 3 (Structure missing)

D

Option 4 (Structure missing)

Step-by-Step Solution

Free-radical substitution reactions typically occur in alkanes or at the alkyl side chains of aromatic hydrocarbons (benzylic positions). These reactions are initiated by the homolytic cleavage of a bond (such as in a halogen molecule) in the presence of heat or ultraviolet light (hνh\nu) to generate free radicals . The reaction proceeds via a chain mechanism involving three main steps: initiation, propagation, and termination . While the benzene ring itself undergoes electrophilic substitution, the alkyl side chain of an alkylbenzene (like toluene) will undergo free-radical substitution upon halogenation in the presence of sunlight.

Note: The specific chemical structures/equations for the options were missing from the input data. Option 1 is marked correct based on the provided probable answer.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Hydrocarbons. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYHydrocarbonsfollowingcorrectexamplefreeradicalsubstitution

More Hydrocarbons Questions

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Phenylacetylene undergoes a reaction with dilute $\text{H}_2\text{SO}_4$ in the presence of $\text{HgSO}_4$ to yield:

A.Option 1 (Structure missing)
B.Option 2 (Structure missing)
C.Option 3 (Structure missing)
D.Option 4 (Structure missing)
MediumSolve

The reaction among the following that proceeds through an electrophilic substitution reaction is:

A.(Option 1 Structure Missing)
B.(Option 2 Structure Missing)
C.4
D.(Option 4 Structure Missing)
EasySolve

The order of decreasing reactivity towards an electrophilic reagent for the following compounds is: (i) Benzene (ii) Toluene (iii) Chlorobenzene (iv) Phenol

A.(i) > (ii) > (iii) > (iv)
B.(ii) > (iv) > (i) > (iii)
C.(iv) > (iii) > (ii) > (i)
D.(iv) > (ii) > (i) > (iii)
MediumSolve

X and Y in the above-mentioned reaction are respectively:

A.X = 2–Butyne; Y = 3–Hexyne
B.X = 2-Butyne; Y = 2-Hexyne
C.X = 1-Butyne; Y = 2-Hexyne
D.X = 1-Butyne; Y = 3–Hexyne
MediumSolve

Match the bond line structures of hydrocarbons given in List-I with the corresponding boiling points given in List-II. List-II (Boiling point in K): (i) 300.9 (ii) 282.5 (iii) 309.1 (iv) 341.9 Choose the correct answer from the options given below:

A.(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
B.(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
C.(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
D.(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
MediumSolve

The dihedral angle of the least stable conformer of ethane is:

A.$60^{\circ}$
B.$0^{\circ}$
C.$120^{\circ}$
D.$180^{\circ}$
EasySolve

Phenanthrene is an aromatic compound and follows Hückel's $(4n+2)\pi$ electron rule. The value of $n$ is:

A.0
B.1
C.2
D.3
MediumSolve

The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is:

A.The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed conformation has no torsional strain.
B.The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has a torsional strain.
C.The staggered conformation of ethane is more stable than eclipsed conformation because staggered conformation has no torsional strain.
D.The staggered conformation of ethane is less stable than eclipsed conformation because staggered conformation has a torsional strain.
EasySolve

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