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NEET CHEMISTRYChemical Bonding and Molecular StructureMedium

Question

The correct bond order in the following species is:

A

O22+>O2+>O2\text{O}_2^{2+} > \text{O}_2^+ > \text{O}_2^-

B

O22+<O2+<O2\text{O}_2^{2+} < \text{O}_2^+ < \text{O}_2^-

C

O2+>O2>O22+\text{O}_2^+ > \text{O}_2^- > \text{O}_2^{2+}

D

O2>O2+>O22+\text{O}_2^- > \text{O}_2^+ > \text{O}_2^{2+}

Step-by-Step Solution

According to Molecular Orbital Theory, the bond order is calculated as 12(NbNa)\frac{1}{2} (N_b - N_a), where NbN_b is the number of bonding electrons and NaN_a is the number of antibonding electrons.

  • O2\text{O}_2: has 16 electrons. Its configuration is σ1s2σ1s2σ2s2σ2s2σ2pz2(π2px2=π2py2)(π2px1=π2py1)\sigma 1s^2 \sigma^* 1s^2 \sigma 2s^2 \sigma^* 2s^2 \sigma 2p_z^2 (\pi 2p_x^2 = \pi 2p_y^2) (\pi^* 2p_x^1 = \pi^* 2p_y^1). Bond order = 1062=2.0\frac{10 - 6}{2} = 2.0.
  • O2+\text{O}_2^+: has 15 electrons (one electron removed from the antibonding π\pi^* orbital). Bond order = 1052=2.5\frac{10 - 5}{2} = 2.5.
  • O22+\text{O}_2^{2+}: has 14 electrons (two electrons removed from the antibonding π\pi^* orbitals). Bond order = 1042=3.0\frac{10 - 4}{2} = 3.0.
  • O2\text{O}_2^-: has 17 electrons (one electron added to the antibonding π\pi^* orbital). Bond order = 1072=1.5\frac{10 - 7}{2} = 1.5. Therefore, the correct decreasing sequence for bond order is O22+(3.0)>O2+(2.5)>O2(1.5)\text{O}_2^{2+} (3.0) > \text{O}_2^+ (2.5) > \text{O}_2^- (1.5).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structurecorrectfollowingspecies

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