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NEET CHEMISTRYChemical Bonding and Molecular StructureMedium

Question

The correct order of bond angles in the following compounds/species is:

A

H2O<NH3<NH4+<CO2H_2O < NH_3 < NH_4^+ < CO_2

B

H2O<NH4+<NH3<CO2H_2O < NH_4^+ < NH_3 < CO_2

C

H2O<NH4+=NH3<CO2H_2O < NH_4^+ = NH_3 < CO_2

D

CO2<NH3<H2O<NH4+CO_2 < NH_3 < H_2O < NH_4^+

Step-by-Step Solution

The bond angles of the given species can be determined using VSEPR theory and hybridisation principles described in the sources:

  1. CO2CO_2: The central carbon atom undergoes spsp hybridisation, resulting in a linear geometry with a bond angle of 180180^\circ .
  2. NH4+NH_4^+: The nitrogen atom is sp3sp^3 hybridised and forms four bond pairs with no lone pairs. This results in a regular tetrahedral geometry with a bond angle of 109.5109.5^\circ .
  3. NH3NH_3: The nitrogen atom is sp3sp^3 hybridised but has three bond pairs and one lone pair. According to the sources, lone pair-bond pair (lp-bp) repulsion is greater than bond pair-bond pair (bp-bp) repulsion, which reduces the ideal tetrahedral angle to 107107^\circ .
  4. H2OH_2O: The oxygen atom is sp3sp^3 hybridised with two bond pairs and two lone pairs. Because lone pair-lone pair (lp-lp) repulsion is even stronger than lp-bp repulsion, the bond angle is further reduced to 104.5104.5^\circ .

Comparing these values, the increasing order of bond angles is: H2O(104.5)<NH3(107)<NH4+(109.5)<CO2(180)H_2O (104.5^\circ) < NH_3 (107^\circ) < NH_4^+ (109.5^\circ) < CO_2 (180^\circ).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structurecorrectanglesfollowingcompoundsspecies

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