Question
Which one of the following statements is true about the structure of ion?
It can be explained by considering hybridisation.
Out of the three bonds, two are longer and one is shorter.
It has three sigma and three -bonds.
All three bonds are equal in length with a bond order in between 1 and 2.
According to the sources, a single Lewis structure for the carbonate ion (), showing one double bond and two single bonds, is inadequate because experimental data proves that all three carbon-to-oxygen bonds are equivalent . This equivalence is explained by resonance, where the ion is a hybrid of three canonical forms . Consequently, all three bonds have the same length, which is intermediate between a single and a double bond, resulting in a bond order between 1 and 2 (specifically 1.33) . Furthermore, the central carbon atom in the carbonate ion is hybridised to maintain its trigonal planar geometry, not . The structure contains three sigma () bonds and one delocalised \pi () bond, rather than three separate -bonds .
This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Organic Chemistry – Some Basic Principles and Techniques . Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.
More Organic Chemistry – Some Basic Principles and Techniques Questions
Which one of the following pairs is isostructural (i.e., having the same shape and hybridization)?
Among the following, isoelectronic species are:
Which one of the following pairs of species have the same bond order?
In a regular octahedral molecule, $MX_{6}$, the number of $X–M–X$ bonds at 180º is:
Which of the following pairs of ions are isoelectronic and isostructural?
Which orbital does the additional electron occupy when $O_{2}$ is converted to the $O_{2}^{-}$ ion?
A species that does not exhibit paramagnetism is:
The total number of $\pi$-bond electrons in the following structure is:
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