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NEET CHEMISTRYThe d-and f-Block ElementsMedium

Question

A set of ions among the following that have a 3d23d^2 electronic configuration is:

A

Ti⁺, V⁴⁺, Cr⁶⁺, Mn⁷⁺

B

Ti⁴⁺, V³⁺, Cr²⁺, Mn³⁺

C

Ti²⁺, V³⁺, Cr⁴⁺, Mn⁵⁺

D

Ti³⁺, V²⁺, Cr³⁺, Mn⁴⁺

Step-by-Step Solution

To determine the electronic configuration of ions, electrons are removed first from the outermost shell (4s) and then from the penultimate shell (3d) .

  1. Titanium (Z=22Z=22): Ground state is [Ar]3d24s2[Ar]3d^2 4s^2. For Ti2+Ti^{2+}, remove 2 electrons from 4s [Ar]3d2\rightarrow [Ar]3d^2.
  2. Vanadium (Z=23Z=23): Ground state is [Ar]3d34s2[Ar]3d^3 4s^2. For V3+V^{3+}, remove 2 electrons from 4s and 1 from 3d [Ar]3d2\rightarrow [Ar]3d^2.
  3. Chromium (Z=24Z=24): Ground state is [Ar]3d54s1[Ar]3d^5 4s^1. For Cr4+Cr^{4+}, remove 1 electron from 4s and 3 from 3d [Ar]3d2\rightarrow [Ar]3d^2.
  4. Manganese (Z=25Z=25): Ground state is [Ar]3d54s2[Ar]3d^5 4s^2. For Mn5+Mn^{5+}, remove 2 electrons from 4s and 3 from 3d [Ar]3d2\rightarrow [Ar]3d^2.

Thus, the set Ti2+,V3+,Cr4+,Mn5+Ti^{2+}, V^{3+}, Cr^{4+}, Mn^{5+} all share the 3d23d^2 configuration.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementsfollowingelectronicconfiguration

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