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NEET CHEMISTRYThe d-and f-Block ElementsMedium

Question

An incorrect statement among the following is :

A

La(OH)3La(OH)_3 is less basic than Lu(OH)3Lu(OH)_3

B

In Lanthanide series, ionic radius of Ln3+Ln^{3+} ions decreases.

C

La is an element of a transition and not of Lanthanide series.

D

The atomic radius of Zr and Hf are the same because of Lanthanide contraction.

Step-by-Step Solution

Due to lanthanoid contraction, the size of Ln3+Ln^{3+} ions decreases regularly from La3+La^{3+} to Lu3+Lu^{3+}. As the size of the cation decreases, the covalent character of the LnOHLn-OH bond increases (according to Fajan's rules). Consequently, the basic strength of the hydroxides steadily decreases from La(OH)3La(OH)_3 to Lu(OH)3Lu(OH)_3. Thus, La(OH)3La(OH)_3 is the most basic and Lu(OH)3Lu(OH)_3 is the least basic. Therefore, the statement 'La(OH)3La(OH)_3 is less basic than Lu(OH)3Lu(OH)_3' is incorrect. The other statements are correct: the ionic radius of Ln3+Ln^{3+} ions decreases along the series , La (Z=57Z=57) is considered a d-block transition element , and the atomic radii of Zr (160 pm) and Hf (159 pm) are almost identical due to lanthanoid contraction .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementsincorrectstatementfollowing

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