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NEET CHEMISTRYHydrocarbonsMedium

Question

Consider the following compounds/species: (Structures missing). The number of compounds/species which obey Hückel's rule is:

A

5

B

4

C

6

D

2

Step-by-Step Solution

According to Hückel's rule, a ring system is considered aromatic if it satisfies the following criteria: (i) Planarity, (ii) Complete delocalisation of the π\pi electrons in the ring, and (iii) Presence of (4n+2)π(4n + 2) \pi electrons in the ring, where nn is an integer (n=0,1,2,n = 0, 1, 2, \dots) . Without the specific structures, we cannot determine exactly which ones obey the rule, but by evaluating each given structure against these three criteria, the total count of aromatic species can be determined.

Note: The specific chemical structures were missing from the input data. The correct option is marked based on the provided probable answer.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Hydrocarbons. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYHydrocarbonsconsiderfollowingcompoundsspeciesstructuresmissing

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Phenylacetylene undergoes a reaction with dilute $\text{H}_2\text{SO}_4$ in the presence of $\text{HgSO}_4$ to yield:

A.Option 1 (Structure missing)
B.Option 2 (Structure missing)
C.Option 3 (Structure missing)
D.Option 4 (Structure missing)
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The reaction among the following that proceeds through an electrophilic substitution reaction is:

A.(Option 1 Structure Missing)
B.(Option 2 Structure Missing)
C.4
D.(Option 4 Structure Missing)
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The order of decreasing reactivity towards an electrophilic reagent for the following compounds is: (i) Benzene (ii) Toluene (iii) Chlorobenzene (iv) Phenol

A.(i) > (ii) > (iii) > (iv)
B.(ii) > (iv) > (i) > (iii)
C.(iv) > (iii) > (ii) > (i)
D.(iv) > (ii) > (i) > (iii)
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X and Y in the above-mentioned reaction are respectively:

A.X = 2–Butyne; Y = 3–Hexyne
B.X = 2-Butyne; Y = 2-Hexyne
C.X = 1-Butyne; Y = 2-Hexyne
D.X = 1-Butyne; Y = 3–Hexyne
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Match the bond line structures of hydrocarbons given in List-I with the corresponding boiling points given in List-II. List-II (Boiling point in K): (i) 300.9 (ii) 282.5 (iii) 309.1 (iv) 341.9 Choose the correct answer from the options given below:

A.(a)-(i), (b)-(iv), (c)-(iii), (d)-(ii)
B.(a)-(iii), (b)-(i), (c)-(iv), (d)-(ii)
C.(a)-(iii), (b)-(iv), (c)-(i), (d)-(ii)
D.(a)-(iv), (b)-(i), (c)-(ii), (d)-(iii)
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The dihedral angle of the least stable conformer of ethane is:

A.$60^{\circ}$
B.$0^{\circ}$
C.$120^{\circ}$
D.$180^{\circ}$
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Phenanthrene is an aromatic compound and follows Hückel's $(4n+2)\pi$ electron rule. The value of $n$ is:

A.0
B.1
C.2
D.3
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The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is:

A.The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed conformation has no torsional strain.
B.The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has a torsional strain.
C.The staggered conformation of ethane is more stable than eclipsed conformation because staggered conformation has no torsional strain.
D.The staggered conformation of ethane is less stable than eclipsed conformation because staggered conformation has a torsional strain.
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