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NEET CHEMISTRYAminesMedium

Question

D is N-methyl aniline in the given below sequence of reaction: AreductionBCHCl3/KOHCreductionDA \xrightarrow{\text{reduction}} B \xrightarrow{CHCl_3/KOH} C \xrightarrow{\text{reduction}} D. Structure of A can be:

A

Option 1 (Missing)

B

Nitrobenzene

C

CH3NH2

D

Option 4 (Missing)

Step-by-Step Solution

Let's deduce the reaction sequence in reverse:

  1. Compound D: Given as N-methyl aniline (C6H5NHCH3C_6H_5-NH-CH_3), which is a secondary amine.
  2. Compound C: Formed by the reaction of B with CHCl3CHCl_3 and KOH, and upon reduction gives D. The reaction of a primary amine with CHCl3/KOHCHCl_3/KOH is the Carbylamine reaction, which yields an isocyanide (RNCR-NC). Reduction of an isocyanide (RNC+4[H]RNHCH3R-NC + 4[H] \rightarrow R-NH-CH_3) always produces a secondary amine with one methyl group. Since D is N-methyl aniline, C must be phenyl isocyanide (C6H5NCC_6H_5-NC).
  3. Compound B: Since B undergoes the carbylamine reaction to form phenyl isocyanide, B must be the corresponding primary aromatic amine, aniline (C6H5NH2C_6H_5-NH_2).
  4. Compound A: A is reduced to form aniline (B). The most common precursor that yields aniline upon reduction is nitrobenzene (C6H5NO2C_6H_5-NO_2).

Therefore, the structure of A is nitrobenzene.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Amines. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAminesnmethylanilinesequencereactionxrightarrowtextreduction

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A.p-Bromoaniline; p-Chloroaniline
B.2,4,6-Tribromoaniline; p-Chloroaniline
C.2,4,6-Tribromoaniline; Benzenediazonium chloride
D.p-Bromoaniline; Benzenediazonium chloride
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Aniline gives a set of the following reactions that yielded a coloured product 'Y'. The structure of 'Y' is: (Note: Reaction scheme is missing from the provided text)

A.Option 1
B.Option 2
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The structure of C in the below-mentioned reaction is: (Note: Reaction scheme is missing from the provided text)

A.Option 1
B.Option 2
C.Option 3
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What results from the electrolytic reduction of nitrobenzene in a highly acidic medium?

A.p-Aminophenol
B.Azoxybenzene
C.Azobenzene
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The reagent required to convert acetamide into methyl amine is:

A.$NaOH/Br_2$
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Which of the following statements about primary amines is false?

A.Alkyl amines are stronger bases than aryl amines
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What is the correct order of the methyl-substituted amines' basic strength in an aqueous solution?

A.$CH_3NH_2 > (CH_3)_2NH > (CH_3)_3N$
B.$(CH_3)_2NH > CH_3NH_2 > (CH_3)_3N$
C.$(CH_3)_3N > CH_3NH_2 > (CH_3)_2NH$
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