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NEET CHEMISTRYThe d-and f-Block ElementsMedium

Question

Given below are two statements: Assertion (A): Ionisation enthalpies of early actinoids are lower than early lanthanoids. Reason (R): Electrons entering 5f5f orbitals in actinoids experience greater shielding from the nuclear charge. In the light of the above statements, choose the most appropriate answer from the options given below:

A

Both (A) and (R) are True and (R) is the correct explanation of (A).

B

Both (A) and (R) are True but (R) is not the correct explanation of (A).

C

(A) is True but (R) is False.

D

(A) is False but (R) is True.

Step-by-Step Solution

Assertion (A) is true: The ionisation enthalpies of the early actinoids are lower than those for the early lanthanoids . Reason (R) is also true and correctly explains (A): When 5f5f orbitals are beginning to be occupied, they penetrate less into the inner core of electrons. Therefore, the 5f5f electrons experience greater (more effective) shielding from the nuclear charge by the inner core compared to the 4f4f electrons of the corresponding lanthanoids. Because these outer electrons are more effectively shielded, they are less firmly held by the nucleus, resulting in lower ionisation enthalpies . (Note: It is important to distinguish that while 5f5f electrons themselves provide poor shielding to other electrons, they experience greater shielding from the inner core).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementsstatementsassertionionisationenthalpiesactinoids

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