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NEET CHEMISTRYP Block ElementsMedium

Question

Identify the correct relationship of stability from the options provided:

A

TlI>TlI3TlI > TlI_3

B

TlCl3>TlClTlCl_3 > TlCl

C

InI3>InIInI_3 > InI

D

AlCl>AlCl3AlCl > AlCl_3

Step-by-Step Solution

In Group 13 elements, the stability of the higher oxidation state (+3) decreases down the group, while the stability of the lower oxidation state (+1) progressively increases due to the inert pair effect (the reluctance of the valence ns2ns^2 electrons to participate in bonding). For the heaviest element, Thallium (Tl), the +1 oxidation state is much more stable than the +3 oxidation state. Therefore, TlITlI is significantly more stable than TlI3TlI_3. Conversely, for lighter elements like Al, the +3 state is most stable, meaning AlCl3>AlClAlCl_3 > AlCl.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from P Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYP Block Elementsidentifycorrectrelationshipstabilityoptions

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