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NEET CHEMISTRYThe d-and f-Block ElementsEasy

Question

Ion that gives colour to water is:

A

Cu+\text{Cu}^+

B

Cr3+\text{Cr}^{3+}

C

Na+\text{Na}^+

D

None of the above

Step-by-Step Solution

The colour of transition metal ions is generally attributed to the presence of unpaired dd-electrons, which undergo ddd-d transitions by absorbing light from the visible region.

  • Cr3+\text{Cr}^{3+} has the electronic configuration [Ar]3d3[\text{Ar}] 3d^3. Because it has 3 unpaired dd-electrons, it undergoes ddd-d transitions and forms a coloured aqueous solution (typically violet or green).
  • Cu+\text{Cu}^+ has the electronic configuration [Ar]3d10[\text{Ar}] 3d^{10}. Since it has a completely filled dd-orbital and no unpaired electrons, it is colourless.
  • Na+\text{Na}^+ has a completely filled noble gas core configuration [Ne][\text{Ne}]. Having no unpaired electrons, it is also colourless.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from The d-and f-Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYThe d-and f-Block Elementscolour

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A.$d^5$ to $d^2$ configuration
B.$d^4$ to $d^5$ configuration
C.$d^3$ to $d^5$ configuration
D.$d^5$ to $d^4$ configuration
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A.High enthalpy of atomization
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C.Colour of hydrated ions
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A.The π-bonding involves the overlap of d-orbitals of oxygen with d-orbitals of manganese.
B.The π-bonding involves the overlap of p-orbitals of oxygen with d-orbitals of manganese.
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The incorrect statement among the following is:

A.Lanthanoids are good conductors of heat and electricity.
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