Match the processes or properties in List-I with their corresponding characteristics in List-II.

List-I (Process/Property) A. Adiabatic process B. Reversible process C. Intensive property D. Extensive property

List-II (Characteristic) I. Independent of the amount of substance II. The reaction can proceed in both directions, from reactants to products and vice versa III. No transfer of heat between the system and the surrounding IV. Dependent on the amount of substance

Choose the correct answer from the options given below:

For the gas phase reaction, $\text{PCl}_5\text{(g)} \rightleftharpoons \text{PCl}_3\text{(g)} + \text{Cl}_2\text{(g)}$, which of the following conditions is correct?

One mole of an ideal gas at $300\text{ K}$ is expanded isothermally from an initial volume of $1\text{ litre}$ to $10\text{ litres}$. The $\Delta E$ for this process is: ($R = 2\text{ cal mol}^{-1}\text{K}^{-1}$)

What is the amount of work done by an ideal gas, if the gas expands isothermally from $10^{-3} \text{ m}^3$ to $10^{-2} \text{ m}^3$ at $300 \text{ K}$ against a constant pressure of $10^5 \text{ N m}^{-2}$?

Match List-I (Equations/Conditions) with List-II (Type of processes) and select the correct option. **List-I (Equations)** (a) $K_p > Q$ (b) $T < \frac{\Delta H}{\Delta S}$ (for $\Delta H > 0$) (c) $K_p = Q$ (d) $T > \frac{\Delta H}{\Delta S}$ (for $\Delta H > 0$) **List-II (Type of processes)** (i) Non-spontaneous (ii) Equilibrium (iii) Spontaneous and endothermic (iv) Spontaneous

The enthalpy of neutralization of which of the following acids and bases is nearly –13.6 Kcal [Roorkee 1999]

The heat of combustion of carbon to $\text{CO}_2$ is $-393.5 \text{ kJ/mol}$. The heat released upon the formation of $35.2 \text{ g}$ of $\text{CO}_2$ from carbon and oxygen gas is:

A system is changed from state A to state B by one path and from B to A by another path. If $E_{1}$ and $E_{2}$ are the corresponding changes in internal energy, then [Pb. PMT 2001]:

The work done to contract a gas in a cylinder is 462 joules. 128 joule energy is evolved in the process. What will be the internal energy change in the process? [MP PMT 2003]