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NEET CHEMISTRYAlcohols, Phenols and EthersMedium

Question

Reagents that can be used to convert alcohols to carboxylic acids are: (A) CrO3H2SO4CrO_3 - H_2SO_4 (B) K2Cr2O7+H2SO4K_2Cr_2O_7 + H_2SO_4 (C) KMnO4+KOH/H3O+KMnO_4 + KOH/H_3O^+ (D) Cu,573KCu, 573 K (E) CrO3+(CH3CO)2OCrO_3 + (CH_3CO)_2O

Choose the most appropriate answer from the options given below:

A

(B), (C) and (D) only

B

(B), (D) and (E) only

C

(A), (B) and (C) only

D

(A), (B) and (E) only

Step-by-Step Solution

To convert primary alcohols directly to carboxylic acids, strong oxidising agents are required.

  1. CrO3H2SO4CrO_3 - H_2SO_4 (Jones Reagent): This is a strong oxidising agent that converts primary alcohols to carboxylic acids.
  2. K2Cr2O7+H2SO4K_2Cr_2O_7 + H_2SO_4 (Acidified Potassium Dichromate): A strong oxidising agent commonly used to oxidise alcohols to carboxylic acids.
  3. KMnO4+KOH/H3O+KMnO_4 + KOH/H_3O^+ (Alkaline KMnO4 followed by acid hydrolysis): A very strong oxidising agent that converts primary alcohols to carboxylic acids.
  4. Cu,573KCu, 573 K: This reagent is used for dehydrogenation. It converts primary alcohols to aldehydes and secondary alcohols to ketones, but does not produce carboxylic acids.
  5. CrO3+(CH3CO)2OCrO_3 + (CH_3CO)_2O: This condition is typically used to stop the oxidation of primary alcohols at the aldehyde stage (by forming gem-diacetates), preventing further oxidation to carboxylic acids.

Therefore, only reagents (A), (B), and (C) are suitable for the conversion to carboxylic acids.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Ethersreagentsconvertalcoholscarboxylicchoose

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