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NEET CHEMISTRYAlcohols, Phenols and EthersEasy

Question

The compound that gives p-cresol with p-methyl diazonium chloride is:

A

H₂O

B

H₃PO₂

C

HCOOH

D

C₆H₅OH

Step-by-Step Solution

To convert a diazonium salt into a phenol, the diazonium group (N2+Cl-N_2^+Cl^-) is replaced by a hydroxyl group (OH-OH). This is achieved by warming the diazonium salt aqueous solution with water (H2OH_2O) or dilute acid.

Reaction: p-CH3C6H4N2+Cl+H2OΔp-CH3C6H4OH (p-Cresol)+N2+HClp\text{-}CH_3-C_6H_4-N_2^+Cl^- + H_2O \xrightarrow{\Delta} p\text{-}CH_3-C_6H_4-OH \text{ (p-Cresol)} + N_2 + HCl

Analysis of other options:

  • H3PO2H_3PO_2 (Hypophosphorous acid): Acts as a reducing agent, replacing the diazonium group with hydrogen (H-H), yielding Toluene.
  • C6H5OHC_6H_5OH (Phenol): Reacts with diazonium salts in a coupling reaction to form azo dyes (e.g., p-hydroxyazobenzene derivative).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Etherscompoundpcresolpmethyldiazoniumchloride

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