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NEET CHEMISTRYElectrochemistryMedium

Question

The concentration of ZnCl2ZnCl_2 solution will change when it is placed in a container which is made of:

A

Al

B

Cu

C

Ag

D

None

Step-by-Step Solution

A metal can displace another metal from its salt solution if it is more reactive, which means it must have a lower standard reduction potential (higher oxidation potential). According to the electrochemical series, Aluminium (Al) is more reactive than Zinc (Zn) because the standard reduction potential of Al (EAl3+/Al=1.66 VE^{\circ}_{Al^{3+}/Al} = -1.66\text{ V}) is lower than that of Zn (EZn2+/Zn=0.76 VE^{\circ}_{Zn^{2+}/Zn} = -0.76\text{ V}) . Therefore, an Aluminium container will react spontaneously with the ZnCl2ZnCl_2 solution (2Al+3Zn2+2Al3++3Zn2Al + 3Zn^{2+} \rightarrow 2Al^{3+} + 3Zn), causing the concentration of the solution to change. On the other hand, Copper (ECu2+/Cu=+0.34 VE^{\circ}_{Cu^{2+}/Cu} = +0.34\text{ V}) and Silver (EAg+/Ag=+0.80 VE^{\circ}_{Ag^{+}/Ag} = +0.80\text{ V}) have higher reduction potentials and are less reactive than zinc, so they will not react with the ZnCl2ZnCl_2 solution .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Electrochemistry. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

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