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NEET CHEMISTRYCoordination CompoundsMedium

Question

CFSE (in the octahedral field) will be maximum in: (Atomic number Co = 27)

A

[Co(H₂O)₆]³⁺

B

[Co(NH₃)₆]³⁺

C

[Co(CN)₆]³⁻

D

[Co(C₂O₄)₃]³⁻

Step-by-Step Solution

Crystal Field Stabilization Energy (CFSE) depends on the magnitude of the crystal field splitting energy (Δo\Delta_o). The value of Δo\Delta_o is directly determined by the field strength of the ligands coordinating to the central metal ion.

  1. Oxidation State: In all the given complexes, Cobalt is in the +3 oxidation state (3d63d^6 configuration).
  2. Spectrochemical Series: According to the spectrochemical series found in the NCERT text, the order of increasing field strength of the ligands involved is: H2O<C2O42<NH3<CNH_2O < C_2O_4^{2-} < NH_3 < CN^-
  3. Conclusion: The cyanide ion (CNCN^-) is the strongest field ligand among the options. It causes the largest splitting of the d-orbitals (maximum Δo\Delta_o). Since CFSE is directly proportional to Δo\Delta_o (specifically for a low-spin d6d^6 complex, CFSE = 2.4Δo-2.4\Delta_o), the complex with the strongest ligand will exhibit the maximum crystal field stabilization energy .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsoctahedralmaximumatomicnumber

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