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NEET CHEMISTRYGeneralMedium

Question

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : In equation ΔrG=nFEcell\Delta_r G = -nFE_{cell} value of ΔrG\Delta_r G depends on n. Reasons R : EcellE_{cell} is an intensive property and ΔrG\Delta_r G is an extensive property. In the light of the above statements, choose the correct answer from the options given below

A

Both A and R are true and R is the correct explanation of A

B

Both A and R are true and R is NOT the correct explanation of A

C

A is true but R is false

D

A is false but R is true

Step-by-Step Solution

Assertion A is true because ΔrG\Delta_r G depends on the number of moles of electrons transferred (nn). Reason R is also true because EcellE_{cell} is an intensive property (independent of amount) and ΔrG\Delta_r G is an extensive property (depends on amount). However, R is not the direct explanation for why ΔrG\Delta_r G depends on nn in the equation, as the dependence on nn is a mathematical consequence of the definition of Gibbs free energy as an extensive property.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from General. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYstatementslabelledassertionlabelledreason

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