back to directory
NEET CHEMISTRYAlcohols, Phenols and EthersMedium

Question

Identify product A and predict the type of reaction in the following transformation: p-O2N-C6H4-Cl(ii) H+(i) NaOH,443KAp\text{-}O_2N\text{-}C_6H_4\text{-}Cl \xrightarrow[\text{(ii) } H^+]{\text{(i) } NaOH, 443 K} A

A

A = p-Nitroaniline, Nucleophilic substitution

B

A = p-Nitrophenol, Electrophilic substitution

C

A = p-Chlorophenol, Elimination

D

A = p-Nitrophenol, Nucleophilic substitution

Step-by-Step Solution

The reaction shows the conversion of p-chloronitrobenzene to p-nitrophenol.

  1. Type of Reaction: This is a Nucleophilic Substitution reaction where the chloride ion (ClCl^-) is replaced by a nucleophile, the hydroxide ion (OHOH^-).
  2. Reactivity: Aryl halides are generally less reactive towards nucleophilic substitution. However, the presence of an electron-withdrawing group (EWG) like NO2-NO_2 at the ortho or para position withdraws electron density from the benzene ring, stabilizing the intermediate carbanion and facilitating the attack of the nucleophile (OHOH^-).
  3. Conditions: While chlorobenzene requires drastic conditions (623 K, 300 atm) to react with NaOH, the presence of the nitro group at the para position lowers the required temperature to 443 K.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Ethersidentifyproductpredictreactionfollowing

More Alcohols, Phenols and Ethers Questions

View all

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →