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NEET CHEMISTRYP Block ElementsMedium

Question

In which of the following pairs, both the species are not isostructural?

A

SiCl4, PCl4+

B

Diamond, silicon carbide

C

NH3, PH3

D

XeF4, XeO4

Step-by-Step Solution

Isostructural species have the same shape and geometry.

  1. XeF4: Xenon undergoes sp3d2 hybridization (4 bond pairs + 2 lone pairs) and has a square planar geometry.
  2. XeO4: Xenon undergoes sp3 hybridization (4 bond pairs + 0 lone pairs) and has a tetrahedral geometry. Since their shapes are different, they are not isostructural. In contrast, SiCl4 and PCl4+ are both tetrahedral (sp3); Diamond and Silicon carbide both have a similar tetrahedral network solid structure; NH3 and PH3 are both trigonal pyramidal (sp3 with 1 lone pair).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from P Block Elements. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYP Block Elementsfollowingspeciesisostructural

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