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NEET CHEMISTRYAlcohols, Phenols and EthersMedium

Question

Iodoform reaction is given by: (a) CH3CH2OHCH_3CH_2OH (b) CH3COCH3CH_3COCH_3 (c) [Compound Missing] (d) CH3OHCH_3OH

A

Only (b)

B

(a), (b) and (c)

C

(a) and (b)

D

(a), (c) and (d)

Step-by-Step Solution

The Iodoform test is positive for compounds containing a methyl ketone group (COCH3-COCH_3) or a methyl carbinol group (CH(OH)CH3-CH(OH)CH_3) attached to at least one hydrogen atom or alkyl/aryl group.

  1. Ethanol (CH3CH2OHCH_3CH_2OH): It contains the CH3CH(OH)CH_3-CH(OH)- group. Upon reaction with iodine and alkali (I2/NaOHI_2/NaOH), it is oxidized to acetaldehyde (CH3CHOCH_3CHO), which contains the CH3C=OCH_3-C=O group, and subsequently yields iodoform (CHI3CHI_3, yellow precipitate).
  2. Acetone (CH3COCH3CH_3COCH_3): It contains the CH3C=OCH_3-C=O group directly. It reacts to form iodoform.
  3. Methanol (CH3OHCH_3OH): It does not contain the requisite methyl group attached to the carbinol carbon. It gives a negative test.

Since both Ethanol (a) and Acetone (b) give the test, the correct selection is '(a) and (b)'.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Ethersiodoformreactionchchohchcochcompound

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