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NEET CHEMISTRYAlcohols, Phenols and EthersMedium

Question

The correct acidic order of the following is: (I) [Structure Missing] (II) [Structure Missing] (III) [Structure Missing]

A

I > II > III

B

III > I > II

C

II > III > I

D

I > III > II

Step-by-Step Solution

The acidic strength of phenols is governed by the stability of the phenoxide ion formed after the loss of a proton.

  1. Electron-Withdrawing Groups (EWG): Substituents like NO2-NO_2, CN-CN, and halogens withdraw electrons from the benzene ring (via I-I and R-R effects). This delocalises the negative charge on the phenoxide oxygen, stabilizing the ion and increasing acidity , .
  2. Electron-Donating Groups (EDG): Substituents like alkyl groups (e.g., CH3-CH_3) or alkoxy groups release electrons (via +I+I or +R+R effects). This intensifies the negative charge on the phenoxide oxygen, destabilizing the ion and decreasing acidity.

Given the correct order III > I > II, it can be inferred that:

  • Compound (III) likely contains an electron-withdrawing group (making it the most acidic).
  • Compound (II) likely contains an electron-donating group (making it the least acidic).
  • Compound (I) is likely the unsubstituted phenol or has an intermediate substituent effect.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Etherscorrectacidicfollowingstructuremissing

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