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NEET CHEMISTRYChemical Bonding and Molecular StructureMedium

Question

The correct order of increasing thermal stability of K2CO3\text{K}_2\text{CO}_3, MgCO3\text{MgCO}_3, CaCO3\text{CaCO}_3 and BeCO3\text{BeCO}_3 is:

A

BeCO3<MgCO3<K2CO3<CaCO3\text{BeCO}_3 < \text{MgCO}_3 < \text{K}_2\text{CO}_3 < \text{CaCO}_3

B

BeCO3<MgCO3<CaCO3<K2CO3\text{BeCO}_3 < \text{MgCO}_3 < \text{CaCO}_3 < \text{K}_2\text{CO}_3

C

MgCO3<BeCO3<CaCO3<K2CO3\text{MgCO}_3 < \text{BeCO}_3 < \text{CaCO}_3 < \text{K}_2\text{CO}_3

D

K2CO3<MgCO3<CaCO3<BeCO3\text{K}_2\text{CO}_3 < \text{MgCO}_3 < \text{CaCO}_3 < \text{BeCO}_3

Step-by-Step Solution

The thermal stability of metal carbonates depends on the polarizing power of the metal cation. A cation with high polarizing power distorts the large carbonate electron cloud (CO32\text{CO}_3^{2-}), making it easier for the compound to decompose into a metal oxide and carbon dioxide on heating.

  1. Alkaline Earth Metal Carbonates: As we move down Group 2 from Be\text{Be} to Ca\text{Ca}, the ionic size increases (Be2+<Mg2+<Ca2+\text{Be}^{2+} < \text{Mg}^{2+} < \text{Ca}^{2+}). This decreases the polarizing power of the cation, thereby increasing the thermal stability of the carbonate. Hence, the order is: BeCO3<MgCO3<CaCO3\text{BeCO}_3 < \text{MgCO}_3 < \text{CaCO}_3.

  2. Alkali vs. Alkaline Earth Metals: Alkali metal cations (like K+\text{K}^+) have a lower charge (+1+1) and larger ionic radius compared to alkaline earth metals. Thus, their polarizing power is much lower. As a result, alkali metal carbonates (except Li2CO3\text{Li}_2\text{CO}_3) are highly stable towards heat and generally do not decompose easily (they melt instead). Therefore, K2CO3\text{K}_2\text{CO}_3 is the most thermally stable compound among the given choices.

The correct increasing order of thermal stability is: BeCO3<MgCO3<CaCO3<K2CO3\text{BeCO}_3 < \text{MgCO}_3 < \text{CaCO}_3 < \text{K}_2\text{CO}_3.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structurecorrectincreasingthermalstabilitytextktextco

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