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NEET CHEMISTRYAlcohols, Phenols and EthersEasy

Question

The correct statement among the following is:

A

Any aldehyde gives secondary alcohol on reduction.

B

The reaction of vegetable oil with H₂SO₄ gives glycerin.

C

C₂H₅OH and iodine with NaOH give iodoform.

D

Sucrose in reaction with NaCl gives invert sugar.

Step-by-Step Solution

  1. Option 1 (Incorrect): Reduction of aldehydes (RCHORCHO) generally yields primary alcohols (RCH2OHRCH_2OH), not secondary alcohols. Secondary alcohols are obtained from the reduction of ketones (RCORRCOR'). (General organic chemistry principles).
  2. Option 2 (Incorrect): Vegetable oils are esters of glycerol (triglycerides). Their hydrolysis (saponification) to give glycerol (glycerin) is typically carried out with bases like NaOH, not concentrated H2SO4H_2SO_4 which is a dehydrating agent.
  3. Option 3 (Correct): Ethanol (C2H5OHC_2H_5OH) contains the methyl carbinol group (CH3CH(OH)CH_3-CH(OH)-). When treated with iodine (I2I_2) and alkali (NaOHNaOH), it undergoes the Iodoform reaction to produce a yellow precipitate of Iodoform (CHI3CHI_3). The reaction is: C2H5OH+4I2+6NaOHCHI3+HCOONa+5NaI+5H2OC_2H_5OH + 4I_2 + 6NaOH \rightarrow CHI_3 + HCOONa + 5NaI + 5H_2O. (This reaction is implicitly supported by the text discussing Iodoform tests for methyl ketones and alcohols ).
  4. Option 4 (Incorrect): Inversion of sucrose (hydrolysis) into glucose and fructose occurs in the presence of acid (H+H^+) or the enzyme invertase, not NaCl .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Alcohols, Phenols and Ethers. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAlcohols, Phenols and Etherscorrectstatementfollowing

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