back to directory
NEET CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Question

The dipole moment of compound AB is 10.92 D and that of compound CD is 12.45 D. If the bond length of AB is 2.72 A˚\text{\AA} and that of CD is 2.56 A˚\text{\AA}, then for these compounds the correct statement is:

A

More ionic nature in AB

B

More ionic nature in CD

C

Equal in both

D

Cannot be predicted

Step-by-Step Solution

The ionic nature of a compound can be assessed by comparing its observed dipole moment to the theoretical dipole moment it would have if the bond were 100% ionic. According to the sources, the dipole moment (μ\mu) is defined as the product of the magnitude of charge (QQ) and the distance of separation (rr), so μ=Q×r\mu = Q \times r . The percentage ionic character is proportional to the ratio of the dipole moment to the bond length (μ/r\mu/r).

  1. For compound AB: The ratio is 10.922.724.015\frac{10.92}{2.72} \approx 4.015 D/A˚\text{\AA}.
  2. For compound CD: The ratio is 12.452.564.863\frac{12.45}{2.56} \approx 4.863 D/A˚\text{\AA}.

Comparing these values, the ratio for compound CD is significantly higher than that for AB. This indicates that for a given bond length, CD has a greater magnitude of charge separation, reflecting a higher percentage of ionic character. Therefore, compound CD exhibits more ionic nature.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Organic Chemistry – Some Basic Principles and Techniques . Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques dipolemomentcompoundcompoundlength

More Organic Chemistry – Some Basic Principles and Techniques Questions

View all

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →