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NEET CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Question

Which of the compounds given below will exhibit a linear structure?

A

NO2NO_{2}

B

HOClHOCl

C

O3O_{3}

D

N2ON_{2}O

Step-by-Step Solution

According to the Valence Shell Electron Pair Repulsion (VSEPR) theory and the concept of hybridisation, the geometry of a molecule is determined by the number of bonding and lone pairs around the central atom:

  1. N2ON_{2}O (Nitrous Oxide): The central nitrogen atom in N2ON_{2}O (NNightarrowON \equiv N ightarrow O) is bonded to two atoms and possesses no lone pairs. This results in spsp hybridisation and a linear structure with a bond angle of 180°, similar to other AB2AB_{2} type molecules like BeCl2BeCl_{2} .
  2. NO2NO_{2} (Nitrogen Dioxide): This is an odd-electron molecule where nitrogen has one lone electron (or effectively one lone pair). This results in a bent or angular geometry due to electron-pair repulsion .
  3. O3O_{3} (Ozone): The central oxygen atom is bonded to two other oxygen atoms and has one lone pair. According to VSEPR theory (AB2EAB_{2}E type), it adopts a bent geometry with an approximate bond angle of 117° .
  4. HOClHOCl (Hypochlorous Acid): In this molecule, the central oxygen atom is bonded to H and Cl and has two lone pairs (AB2E2AB_{2}E_{2} type). Like water, this results in a bent (V-shaped) geometry .

Therefore, only N2ON_{2}O exhibits a linear structure.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Organic Chemistry – Some Basic Principles and Techniques . Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

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