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NEET CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Question

Which of the following is a polar molecule?

A

SF₄

B

SiF₄

C

XeF₄

D

BF₃

Step-by-Step Solution

  1. Analyze BF3BF_3: Boron has 3 valence electrons and forms 3 bonds. The molecule is Trigonal Planar and symmetrical. The bond dipoles cancel out (mu=0\\mu = 0). Non-polar.
  2. Analyze SiF4SiF_4: Silicon has 4 valence electrons and forms 4 bonds. The molecule is Tetrahedral and symmetrical. The bond dipoles cancel out (mu=0\\mu = 0). Non-polar.
  3. Analyze XeF4XeF_4: Xenon has 8 valence electrons. It forms 4 bonds and has 2 lone pairs. The geometry is Square Planar (lone pairs are at 180^\\circ). The symmetry causes bond dipoles to cancel (mu=0\\mu = 0). Non-polar.
  4. Analyze SF4SF_4: Sulfur has 6 valence electrons. It forms 4 bonds with Fluorine, leaving 1 lone pair. The electron geometry is trigonal bipyramidal, and the molecular shape is See-Saw (asymmetrical). The dipole moments do not cancel (muneq0\\mu \\neq 0). It is polar.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Organic Chemistry – Some Basic Principles and Techniques . Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

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