back to directory
NEET CHEMISTRYChemical Bonding and Molecular StructureMedium

Question

Which statement about peptide bonds is NOT true?

A

C–N bond length in proteins is longer than the usual bond length of the C–N single bond.

B

Spectroscopic analysis shows the planar structure of the peptide group.

C

C–N bond length in proteins is smaller than the usual bond length of the C–N single bond.

D

None of the above.

Step-by-Step Solution

Proteins are linear polymers of amino acids linked together by peptide bonds . A peptide bond (–CO–NH–) exhibits resonance, where the lone pair of electrons on the nitrogen atom is delocalised into the carbonyl group . This resonance gives the C–N bond partial double bond character . According to the principles of chemical bonding, bond lengths in resonance hybrids are intermediate between single and double bonds . Specifically, as bond order increases, bond length decreases . In the sources, a typical C–N single bond length is 143 pm, while a C=N double bond is 138 \pm . Due to its partial double bond character, the C–N bond in a peptide is shorter (typically around 132 pm) than a standard C–N single bond . Therefore, the statement that the bond is longer is incorrect. Additionally, this resonance restricts rotation about the bond, resulting in a planar geometry for the peptide group .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structurestatementpeptide

More Chemical Bonding and Molecular Structure Questions

View all

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →