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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Match List-I (Molecules) with List-II (Shapes): List-I: (a) $PCl_5$ (b) $SF_6$ (c) $BrF_5$ (d) $BF_3$ List-II: (i) Square pyramidal (ii) Trigonal planar (iii) Octahedral (iv) Trigonal bipyramidal Choose the correct answer from the options given below:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

The correct order of ionic character among CaH$$_2$$, BeH$$_2$$ and BaH$$_2$$ is:

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CHEMISTRYChemical KineticsEasy

For the reaction $2A \rightarrow B + C$, it would be a zero-order reaction when:

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CHEMISTRYChemical KineticsMedium

The rate of the reaction $2N_2O_5 \rightarrow 4NO_2 + O_2$ can be written in three ways: $-\frac{d[N_2O_5]}{dt} = k[N_2O_5]$ $\frac{d[NO_2]}{dt} = k'[N_2O_5]$ $\frac{d[O_2]}{dt} = k''[N_2O_5]$ The relationship between $k$ and $k'$ and between $k$ and $k''$ are:

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BIOLOGYMolecular Basis of InheritanceEasy

E.coli has only 4.6 × 10^6 base pairs and completes the process of replication within 18 minutes, then the average rate of polymerization is approximately:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The correct order of bond angles in the following compounds/species is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Paramagnetic species among the following is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The correct order of increasing thermal stability of $\text{K}_2\text{CO}_3$, $\text{MgCO}_3$, $\text{CaCO}_3$ and $\text{BeCO}_3$ is:

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CHEMISTRYChemical KineticsEasy

In the reaction, $3A \rightarrow 2B$ the rate of reaction $+\frac{d[B]}{dt}$ is equal to:

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CHEMISTRYSolutionsEasy

Beans get cooked earlier in a pressure cooker, because:

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CHEMISTRYChemical KineticsMedium

The activation energy for a simple chemical reaction $A \rightarrow B$ is $E_a$ in a forward direction. The activation energy for the reverse reaction:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

The correct shape and hybridisation of BrF$_5$ is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Easy

The correct order of electronegativity of hybrid orbitals of carbon is:

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CHEMISTRYChemical KineticsMedium

If the rate of reaction doubles when the temperature is raised from $20^\circ\text{C}$ to $35^\circ\text{C}$, then the activation energy for the reaction will be : ($R = 8.314 \text{ J mol}^{-1} \text{ K}^{-1}$)

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CHEMISTRYChemical KineticsMedium

If a first-order reaction reaches 60% completion within 60 minutes, approximately how much time would it take for the same reaction to reach 50% completion? ($\log 4=0.60$, $\log 5=0.69$)

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CHEMISTRYChemical KineticsMedium

For the reaction, $5Br^- + BrO_3^- + 6H^+ \rightarrow 3Br_2 + 3H_2O$, the correct representation of the consumption and formation of reactants and products is:

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CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Which one of the following statements is correct?

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CHEMISTRYChemical KineticsMedium

A reaction having equal energies of activation for forward and reverse reactions has

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CHEMISTRYChemical KineticsEasy

Half-life period of a first order reaction is $1386 \text{ s}$. The specific rate constant of the reaction is:

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BIOLOGYHard

Use of an artificial kidney during hemodialysis may result in : (a) Nitrogenous waste build-up in the body (b) Non-elimination of excess potassium ions (c) Reduced absorption of calcium ions from gastro-intestinal tract (d) Reduced RBC production. Which of the following options is the most appropriate?

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