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NEET CHEMISTRYCoordination CompoundsMedium

Question

Among [Ni(CO)4][Ni(CO)_4], [Ni(CN)4]2[Ni(CN)_4]^{2-}, [NiCl4]2[NiCl_4]^{2-} species, the hybridization states of the Ni atom are respectively: (At. No. of Ni = 28)

A

sp3,dsp2,sp3sp^3, dsp^2, sp^3

B

sp3,sp3,dsp2sp^3, sp^3, dsp^2

C

dsp2,sp3,sp3dsp^2, sp^3, sp^3

D

sp3,dsp2,dsp2sp^3, dsp^2, dsp^2

Step-by-Step Solution

Let us find the hybridization of the central metal atom in each complex:

  1. In [Ni(CO)4][Ni(CO)_4], Ni is in the 00 oxidation state with the electronic configuration [Ar]3d84s2[Ar] 3d^8 4s^2. CO is a strong field ligand, which forces the pairing of 4s4s electrons into the 3d3d orbitals, resulting in a 3d103d^{10} configuration. The one 4s4s and three 4p4p orbitals undergo sp3sp^3 hybridization, making it a tetrahedral complex.
  2. In [Ni(CN)4]2[Ni(CN)_4]^{2-}, Ni is in the +2+2 oxidation state with the configuration [Ar]3d8[Ar] 3d^8. The CNCN^- ion is a strong field ligand, which causes the pairing of the two unpaired 3d3d electrons, leaving one 3d3d orbital empty. The empty 3d3d, one 4s4s, and two 4p4p orbitals undergo dsp2dsp^2 hybridization, resulting in a square planar geometry.
  3. In [NiCl4]2[NiCl_4]^{2-}, Ni is in the +2+2 oxidation state with the configuration [Ar]3d8[Ar] 3d^8. The ClCl^- ion is a weak field ligand, so it cannot cause the pairing of the 3d3d electrons. The one 4s4s and three 4p4p orbitals undergo sp3sp^3 hybridization, leading to a tetrahedral geometry. Therefore, the hybridization states are sp3,dsp2,sp3sp^3, dsp^2, sp^3 respectively.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsspecieshybridizationstatesrespectively

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