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NEET CHEMISTRYChemical Bonding and Molecular StructureEasy

Question

Among the following, the compound that is electron deficient is:

A

BaCl2BaCl_{2}

B

BCl3BCl_{3}

C

CCl4CCl_{4}

D

PCl5PCl_{5}

Step-by-Step Solution

According to the octet rule, atoms generally form bonds to achieve a stable configuration of eight electrons in their valence shell . However, there are several exceptions to this rule . One such exception is the incomplete octet of the central atom, which is characteristic of electron-deficient compounds . In BCl3BCl_{3}, the central boron atom has three valence electrons and forms three covalent bonds with chlorine atoms. This results in a total of only six electrons surrounding the boron atom . Since this is fewer than the eight electrons required for an octet, BCl3BCl_{3} is electron deficient. In contrast, CCl4CCl_{4} follows the octet rule with eight electrons, and PCl5PCl_{5} represents an 'expanded octet' with ten electrons .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

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