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NEET CHEMISTRYCoordination CompoundsMedium

Question

An ion, among the following, that has a magnetic moment of 2.84 BM is: (At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27)

A

Ni²⁺

B

Ti³⁺

C

Cr²⁺

D

Co²⁺

Step-by-Step Solution

The 'spin-only' magnetic moment (μ\mu) is calculated using the formula: μ=n(n+2)\mu = \sqrt{n(n+2)} B.M., where 'nn' is the number of unpaired electrons.

Given μ=2.84\mu = 2.84 B.M., we can calculate nn: n(n+2)2.84\sqrt{n(n+2)} \approx 2.84 n(n+2)8n(n+2) \approx 8 For n=2n = 2, 2(4)=82.83\sqrt{2(4)} = \sqrt{8} \approx 2.83 B.M. Thus, the ion must have 2 unpaired electrons.

Now, let's analyze the electronic configurations of the given ions:

  1. Ni2+Ni^{2+} (Z=28): Configuration is [Ar]3d8[Ar] 3d^8. The d-orbitals have the arrangement \uparrow\downarrow \uparrow\downarrow \uparrow\downarrow \uparrow \uparrow. This gives 2 unpaired electrons. (Calculated μ2.84\mu \approx 2.84 B.M.)
  2. Ti3+Ti^{3+} (Z=22): Configuration is [Ar]3d1[Ar] 3d^1. This gives 1 unpaired electron. (Calculated μ=1.73\mu = 1.73 B.M.)
  3. Cr2+Cr^{2+} (Z=24): Configuration is [Ar]3d4[Ar] 3d^4. This gives 4 unpaired electrons. (Calculated μ=4.90\mu = 4.90 B.M.)
  4. Co2+Co^{2+} (Z=27): Configuration is [Ar]3d7[Ar] 3d^7. This gives 3 unpaired electrons. (Calculated μ=3.87\mu = 3.87 B.M.)

Therefore, Ni2+Ni^{2+} is the correct answer .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsfollowingmagneticmoment

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