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NEET CHEMISTRYCoordination CompoundsMedium

Question

Copper sulphate dissolves in excess of KCN to give:

A

CuCN

B

[Cu(CN)₄]³⁻

C

[Cu(CN)₄]²⁻

D

Cu(CN)₂

Step-by-Step Solution

The reaction proceeds in two steps involving a redox change followed by complex formation:

  1. Redox Reaction: When KCNKCN is added to Copper sulphate (CuSO4CuSO_4), the Cu2+Cu^{2+} ions are first reduced to Cu+Cu^+ ions by the cyanide ions (similar to the reaction of Cu2+Cu^{2+} with II^- described in the source). The unstable Cu(CN)2Cu(CN)_2 decomposes to give a white precipitate of Copper(I) cyanide (CuCNCuCN) and cyanogen gas (CN)2(CN)_2. 2Cu2++4CN2CuCN(s)+(CN)2(g)2Cu^{2+} + 4CN^- \rightarrow 2CuCN(s) + (CN)_2(g)
  2. Complex Formation: In the presence of excess KCN, the insoluble CuCNCuCN precipitate dissolves to form a stable soluble complex, potassium tetracyanidocuprate(I). CuCN(s)+3CN(aq)[Cu(CN)4]3(aq)CuCN(s) + 3CN^-(aq) \rightarrow [Cu(CN)_4]^{3-}(aq)

This specific reaction is highlighted in NCERT Exercise 5.14, asking for the coordination entity formed under these conditions . The resulting complex ion is [Cu(CN)4]3[Cu(CN)_4]^{3-}, where Copper is in the +1 oxidation state.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundscoppersulphatedissolvesexcess

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