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NEET CHEMISTRYCoordination CompoundsMedium

Question

Given below are two statements: Statement I: Both [Co(NH3)6]3+[Co(NH_3)_6]^{3+} and [CoF6]3[CoF_6]^{3-} complexes are octahedral but differ in their magnetic behaviour. Statement II: [Co(NH3)6]3+[Co(NH_3)_6]^{3+} is diamagnetic whereas [CoF6]3[CoF_6]^{3-} is paramagnetic. In the light of the above statements, choose the correct answer from the options given below:

A

Both Statement I and Statement II are False.

B

Statement I is True and Statement II is False.

C

Statement I is False but Statement II is True.

D

Both Statement I and Statement II are True.

Step-by-Step Solution

Both [Co(NH3)6]3+[Co(NH_3)_6]^{3+} and [CoF6]3[CoF_6]^{3-} have the central metal ion CoCo in the +3 oxidation state, which has a 3d63d^6 electronic configuration. In [Co(NH3)6]3+[Co(NH_3)_6]^{3+}, NH3NH_3 acts as a strong field ligand, causing the pairing of 3d3d electrons against Hund's rule. This results in a t2g6eg0t_{2g}^6 e_g^0 configuration with no unpaired electrons. It undergoes d2sp3d^2sp^3 hybridization, forming an inner-orbital octahedral complex that is diamagnetic. In [CoF6]3[CoF_6]^{3-}, FF^- is a weak field ligand and does not cause the pairing of 3d3d electrons. It has a t2g4eg2t_{2g}^4 e_g^2 configuration with four unpaired electrons. It undergoes sp3d2sp^3d^2 hybridization, forming an outer-orbital octahedral complex that is highly paramagnetic. Therefore, both complexes are octahedral but have different magnetic behaviours, making both Statement I and Statement II true.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Coordination Compounds. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYCoordination Compoundsstatementsstatementcomplexesoctahedraldiffer

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