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NEET CHEMISTRYChemical Bonding and Molecular StructureMedium

Question

Identify the incorrect statement among the following options:

A

O2+O_2^+ ion is diamagnetic.

B

The bond orders of O2+O_2^+, O2O_2, O2O_2^- and O22O_2^{2-} are 2.5, 2, 1.5, and 1, respectively.

C

C2C_2 molecule has four electrons in its two degenerate π\pi molecular orbitals.

D

H2+H_2^+ ion has one electron.

Step-by-Step Solution

According to Molecular Orbital Theory (MOT):

  1. Magnetism of O2+O_2^+: The oxygen molecule (O2O_2) has 16 electrons and is paramagnetic because it contains two unpaired electrons in its π2px\pi^* 2p_x and π2py\pi^* 2p_y antibonding orbitals . When O2O_2 loses an electron to form the O2+O_2^+ ion, the electron is removed from one of these antibonding orbitals, leaving one unpaired electron behind. Since species with unpaired electrons are paramagnetic, O2+O_2^+ is paramagnetic, not diamagnetic . This makes Option 1 incorrect.
  2. Bond Orders: Bond order is calculated as 12(NbNa)\frac{1}{2}(N_b - N_a) . For O2O_2 (16e), BO=2BO = 2; for O2+O_2^+ (15e), BO=2.5BO = 2.5; for O2O_2^- (17e), BO=1.5BO = 1.5; and for O22O_2^{2-} (18e), BO=1.0BO = 1.0 . This statement is correct.
  3. C2C_2 Molecule: C2C_2 has 12 electrons with the configuration (σ1s)2(σ1s)2(σ2s)2(σ2s)2(π2px2=π2py2)(\sigma 1s)^2 (\sigma^* 1s)^2 (\sigma 2s)^2 (\sigma^* 2s)^2 (\pi 2p_x^2 = \pi 2p_y^2) . It indeed has four electrons in its two degenerate π\pi molecular orbitals. This statement is correct.
  4. H2+H_2^+ Ion: A neutral hydrogen atom has one electron; a H2H_2 molecule has two . The H2+H_2^+ ion is formed by removing one electron from the H2H_2 molecule, leaving it with exactly one electron . This statement is correct.

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Chemical Bonding and Molecular Structure. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYChemical Bonding and Molecular Structureidentifyincorrectstatementfollowingoptions

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