back to directory
NEET CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques Medium

Question

If the main axis of a diatomic molecule is z, then the molecular orbital pxp_x and pyp_y overlap to form which of the following orbital:

A

π\pi molecular orbital

B

σ\sigma molecular orbital

C

δ\delta molecular orbital

D

No bond will form

Step-by-Step Solution

According to Molecular Orbital Theory (MOT), atomic orbitals must possess the same symmetry about the molecular axis to combine and form molecular orbitals . By convention, the z-axis is taken as the internuclear (molecular) axis . The pxp_x and pyp_y orbitals are mutually perpendicular, oriented along the x and y axes respectively . Because they have different symmetries relative to the z-axis, their overlap is zero, and they cannot undergo linear combination to form a bond .

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Organic Chemistry – Some Basic Principles and Techniques . Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYOrganic Chemistry – Some Basic Principles and Techniques diatomicmoleculemolecularorbitaloverlap

More Organic Chemistry – Some Basic Principles and Techniques Questions

View all

Which one of the following pairs is isostructural (i.e., having the same shape and hybridization)?

A.$\text{BCl}_3$ and $\text{BrCl}_3$
B.$\text{NH}_3$ and $\text{NO}_3^-$
C.$\text{NF}_3$ and $\text{BF}_3$
D.$\text{BF}_4^-$ and $\text{NH}_4^+$
MediumSolve

Among the following, isoelectronic species are:

A.$CO_{2}, NO_{2}$
B.$NO_{2}^{-}, CO_{2}$
C.$CN^{-}, CO$
D.$SO_{2}, CO_{2}$
EasySolve

Which one of the following pairs of species have the same bond order?

A.$\text{CO}$, $\text{NO}$
B.$\text{O}_2^-$, $\text{CN}^-$
C.$\text{CN}^-$, $\text{NO}^+$
D.$\text{N}^+$, $\text{CN}^+$
MediumSolve

In a regular octahedral molecule, $MX_{6}$, the number of $X–M–X$ bonds at 180º is:

A.Two
B.Six
C.Four
D.Three
EasySolve

Which of the following pairs of ions are isoelectronic and isostructural?

A.CO₃²⁻, SO₃²⁻
B.ClO₃⁻, CO₃²⁻
C.SO₃²⁻, NO₃⁻
D.ClO₃⁻, SO₃²⁻
MediumSolve

Which orbital does the additional electron occupy when $O_{2}$ is converted to the $O_{2}^{-}$ ion?

A.$\pi$ orbital
B.$\sigma^{*}$ orbital
C.$\sigma$ orbital
D.$\pi^{*}$ orbital
MediumSolve

A species that does not exhibit paramagnetism is:

A.$N_{2}^{+}$
B.$O_{2}^{-}$
C.$CO$
D.$NO$
MediumSolve

The total number of $\pi$-bond electrons in the following structure is:

A.4
B.8
C.12
D.16
EasySolve

Why 32,000+ students choose TopperSquare

Everything you need to crack NEET

15,000+ Chapter MCQs

Physics, Chemistry, Biology — chapter-wise, topic-wise practice

AI Performance Analytics

Know your weak topics. Get a personalised study plan.

Full NEET Mock Tests

180 questions, timed, with detailed score analysis

PYQ Sets 2010–2024

15 years of past papers with solved explanations

Start Practising Free

No credit card · 30-second signup · Free forever plan included

This neet chemistry practice question is part of the TopperSquare free question bank. TopperSquare offers 15,000+ chapter-wise NEET MCQs across Physics, Chemistry, and Biology with detailed step-by-step explanations, full mock tests, NEET PYQs (2010–2024), and an AI-powered performance analytics dashboard. browse all neet practice questions → · practice chemistry sets →

Explore more subjects:Physics MCQs•Chemistry MCQs•Biology MCQs•Botany MCQs•Zoology MCQs•NEET Mock Tests•NEET PYQs