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NEET CHEMISTRYAminesMedium

Question

Match Column-I (Reaction) with Column-II (Product formed) and mark the appropriate choice:

Column-I (Reaction) (a) Gabriel synthesis (b) Kolbe synthesis (c) Williamson synthesis (d) Etard reaction

Column-II (Product formed) (i) Benzaldehyde (ii) Ethers (iii) Primary amines (iv) Salicylic acid

A

(a)-(iii), (b)-(i), (c)-(ii), (d)-(iv)

B

(a)-(ii), (b)-(iii), (c)-(i), (d)-(iv)

C

(a)-(iv), (b)-(iii), (c)-(i), (d)-(ii)

D

(a)-(iii), (b)-(iv), (c)-(ii), (d)-(i)

Step-by-Step Solution

Let's match each name reaction with its corresponding product:

  1. Gabriel phthalimide synthesis: This reaction is used exclusively for the preparation of pure aliphatic primary amines from alkyl halides.
  2. Kolbe synthesis: In this reaction, phenol is treated with sodium hydroxide and CO2CO_2, followed by acidification, to yield 2-hydroxybenzoic acid, commonly known as salicylic acid.
  3. Williamson synthesis: This is a classic method for the preparation of symmetrical and unsymmetrical ethers by reacting an alkyl halide with a sodium alkoxide.
  4. Etard reaction: This reaction involves the partial oxidation of toluene using chromyl chloride (CrO2Cl2CrO_2Cl_2) to form benzaldehyde.

Therefore, the correct matching is (a)-(iii), (b)-(iv), (c)-(ii), (d)-(i).

Exam Context & Concepts Covered

This question aligns with the NEET CHEMISTRY syllabus, specifically targeting concepts from Amines. Mastering this topic is crucial for scoring well in the upcoming medical entrance examinations. Solving conceptually related problems will help you understand the nuances of these concepts and improve your problem-solving speed.

CHEMISTRYAminescolumnireactioncolumniiproductformed

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The products formed when Aniline reacts with $Br_2$ water, and $NaNO_2/HCl$ will be, respectively:

A.p-Bromoaniline; p-Chloroaniline
B.2,4,6-Tribromoaniline; p-Chloroaniline
C.2,4,6-Tribromoaniline; Benzenediazonium chloride
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Aniline gives a set of the following reactions that yielded a coloured product 'Y'. The structure of 'Y' is: (Note: Reaction scheme is missing from the provided text)

A.Option 1
B.Option 2
C.Option 3
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A.Option 1
B.Option 2
C.Option 3
D.Option 4
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What results from the electrolytic reduction of nitrobenzene in a highly acidic medium?

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B.Azoxybenzene
C.Azobenzene
D.Aniline
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The reagent required to convert acetamide into methyl amine is:

A.$NaOH/Br_2$
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A.Option 1 (Missing)
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Which of the following statements about primary amines is false?

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